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山东理工大学化学工程学院

办公地点:山东理工大学西校区4号实验楼416

通讯地址:山东省淄博市张店区张周路12号山东理工大学化工学院

联系电话13964475948

电子邮箱huiliu1030@sdut.edu.cn,huiliu1030@163.com

邮编:255049


教育与科研经历:

2013.11-2014.11,法国原子能委员会(CEA)和牛津大学,有机化学,博士后,导师:Frederic Taran教授和Véronique Gouverneur教授

2013.10-至今,山东理工大学化学工程学院,讲师

2012.3-2013.10,华东师范大学绿色化学与化工过程绿色化重点实验室,有机化学,博士后,导师:姜雪峰研究员

2009.5-2010.4,美国GlaxoSmithKline (葛兰素史克)研发部,访问学者

2006.9-2012.3,华东理工大学精细化工研究所,应用化学,博士,导师:童晓峰教授和王利民教授

2002.9-2006.7,曲阜师范大学化学与化工学院,学士。


研究方向:

1.金属导向的有机合成方法学研究

2.18F标记的PET药物研发以及在医药领域中的创新应用

3.精细化工产品和医药中间体的合成路线以及合成工艺的研发


承担的科研项目:

1.国家自然科学基金青年基金:21302057(主持)

2.中国博士后面上基金:2012M520858(主持)

3.中央高校基本科研业务费专项资金(华东师范大学)(主持)

4.山东理工大学青年教师发展支持计划(2014.1-2016.12),(主持)

5.山东理工大学博士启动基金,2013,(主持)

6.国家自然科学基金青年基金:21405095(第二承担人)


获奖情况:

上海市优秀毕业生(2012)

天鼎-东岳特等奖学金(2011)

华东理工大学高水平文章奖学金(2011)

山东省优秀毕业生(2006)

山东省优秀学生(2003)

发表论文:

21.  E. Decuypere, S. Specklin, S. Gabillet, D. Audisio,H. Liu, L. Plougastel, S. Kolodych, F. Taran. Copper(I)-Catalyzed Cycloaddition of 4-Bromosydnones and Alkynes for the Regioselective Synthesis of 1,4,5-Trisubstituted Pyrazoles.Org. Lett. 2015,17, 362-365.

20. H. Liu, J. Wei, Z. Qiao, Y. Fu, X. Jiang*. Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp2-Csp3 Bond Formation.Chem. Eur. J.2014, 20,8308-8313.

19. H. Liu, M. Feng, X. Jiang*. Unstrained Carbon-Carbon Bond Cleavage.Chem. Asian J. 2014, 9, 3360-3382.

18. H. Liu,X. Jiang*. Pd-Catalyzed Reactions from Unactivated Csp3-I Bond.Pure and Applied Chemistry.2014,85, PAC.2014.5032.

17.  Z. Qiao,§H. Liu,§X. Xiao, Y. Fu, J. Wei, Y. Li* and X. Jiang*.Efficient Access to 1, 4-Benzothiazine: Palladium-Catalyzed Double C-S Bond Formation Using Na2S2O3as Sulfuration Reagent.Org. Lett.2013‚15‚ 2594-2597.

16. H. Liu, Z. Gu and X. Jiang*. Direct Trifluoromethylation of C-H Bond.Adv. Synth. Catal.2013, 355,617-626.

15. H. Liu, Xuefeng Jiang*.Transfer of Sulfur:From Simple to Diverse.Chem.Asian J.2013,8, 2546-2563.

14. H. Liu, X. Jiang*.Mechanistic Insight to the Reaction Pathway of Aerobic Oxidative C-C Bond Cleavage ofα-Hydroxy Ketones.Synlett,2013,24, 1311-1315.

13. L. Wang, J. Huang,S. Peng,H. Liu, X. Jiang*and J. Wang*.Palladium-Catalyzed Oxidative Cycloaddition via C–H/N–H Activation: Access to Benzazepines.Angew. Chem. Int. Ed.2013,52, 1768-1772.

12. H. Liu, C. Dong, Z. Zhang, P. Wu and X. Jiang*. Transition-Metal-Free Aerobic Oxidative Cleavage of C-C Bonds inα-Hydroxy Ketones and Mechanistic Insight to the Reaction Pathway.Angew. Chem. Int. Ed.2012,51, 12570-12574.

11. H. Liu,Z. Qiao and X. Jiang*. Palladium-Catalyzed Atom Transfer Radical Cyclization of Unactivated Alkyl Iodide.Org. Biomol. Chem.2012,10, 7274-7277.

10. X. Jiang*,H. Liu and Z. Gu.Carbon-Halogen Bond Formation by the Reductive Elimination of PdIISpecies.Asian J. Org. Chem.2012,1, 16-24.

9. K. Li, J. Hu, H. Liu and X. Tong*. Amine-catalyzed formal (3+3) annulations of 2-(acetoxymethyl)buta-2,3-dienoate with sulfur ylides: synthesis of 4H-pyrans bearing a vinyl sulfide group.Chem. Commun.2012,48, 2900-2902.

8. W. Li, H. Liu, X. Jiang*, J. Wang*.Enantioselective Organocatalytic Conjugate Addition of Nitroalkanes to Electrophilic 2-Iminochromenes. ACS Catal. 2012,2, 1535-1538.

7. X. Jiang*, L. Shi, H. Liu, Akbar H. Khan and Jason S. Chen. Gas Extrusion in Natural Products Total Synthesis.Org. Biomol. Chem.2012,10,8383-8392.

6. P. Wu, H. Liu, X. Tong*.Synthesis of 3-pyrrolineviadomino Heck-aza-Michael reaction.Tetrahedron Lett.2012,53,4673-4675.

5. Q. Ren, J. Huang, L. Wang, W. Li, H. Liu,X. Jiang*and J. Wang*. Highly Efficient Assembly of 3‑Hydroxy Oxindole Scaffold via a Catalytic Decarboxylative [1,2]-Addition Strategy.ACS Catalysis,2012,2, 2622-2625.

4. H. Liu, C. Li, D. Qiu*and X. Tong*.Palladium-Catalyzed Cycloisomerizations of (Z)-1-Iodo-1,6-dienes: Iodine Atom Transfer and Mechanistic Insight to Alkyl Iodide Reductive Elimination.

J. Am. Chem. Soc.2011,133, 6187-6193.

3. H. Liu, C. Chen, L. Wang and X. Tong*. Pd(0)-Catalyzed Iodoalkynation of Norbornene Scaffolds: The Remarkable Solvent Effect on Reaction Pathway.Org. Lett.2011,13, 5072-5075.

2. H. Liu, L. Wang and X. Tong*. Palladium-Catalyzed Heck-type Reaction of Oxime Ether Bearing a Pendant Vinyl Iodide Moiety.Chem.Comm.2011,47, 12206-12208.

1. H. Liu, J. Yu, L. Wang, X. Tong*.Cyclization–oxidation of 1,6-enyne derivatived from Baylis–Hillman adducts via Pd(II)/Pd(IV)-catalyzed reactions: stereoselective synthesis of multi-substituted bicyclo[3.1.0] hexanes and insight into reaction pathways. Tetrahedron Lett. 2008, 49, 6924–6928.

授权专利:

1.姜雪峰,汪舰,刘会,李文军,3,3-二取代-2-氧化吲哚类化合物的不对称合成方法。专利授权号:ZL 2012 1 0093045.9

2.姜雪峰,刘会,乔宗君,一种2,3-二氢-[1,4]-苯并噻嗪类化合物的合成方法。专利授权号:ZL 2013 1 0028082.6


著作:

1.Hui Liu, X. Jiang*.

Application of Zinc catalysts in Total Synthesis in Zinc Catalysis-Applications in Organic Synthesis Ed. Stephan Enthaler and Xiao-Feng Wu, Wiley-VCH, 2014, 219-273.

2. X. Jiang*, Hui Liu

Electrophilic Cyclizations in Comprehensive Organic Synthesis 2nd Edition, Ed. Gary Molander and Paul Knochel, Oxford: Elsevier, 2014, Vol 4, 412-497.


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